Nature Communications (Apr 2023)

Br−/BrO−-mediated highly efficient photoelectrochemical epoxidation of alkenes on α-Fe2O3

  • Yukun Zhao,
  • Mengyu Duan,
  • Chaoyuan Deng,
  • Jie Yang,
  • Sipeng Yang,
  • Yuchao Zhang,
  • Hua Sheng,
  • Youji Li,
  • Chuncheng Chen,
  • Jincai Zhao

DOI
https://doi.org/10.1038/s41467-023-37620-8
Journal volume & issue
Vol. 14, no. 1
pp. 1 – 9

Abstract

Read online

Alkene epoxidation, whose products are important intermediates for the manufacture of pharmaceuticals and epoxy resins, has attracted extensive attention. Unlike the conventional electrochemical Br−/Br2-mediated epoxidation, here the authors report a photoelectrochemical Br−/BrO−- mediated system to achieve efficient epoxidation performance on α-Fe2O3.