Dichloromethylation of enones by carbon nitride photocatalysis

Stefano Mazzanti; Bogdan Kurpil; Bartholomäus Pieber; Markus Antonietti; Aleksandr Savateev

doi:10.1038/s41467-020-15131-0

Nature Communications (Mar 2020)

Dichloromethylation of enones by carbon nitride photocatalysis

Stefano Mazzanti,
Bogdan Kurpil,
Bartholomäus Pieber,
Markus Antonietti,
Aleksandr Savateev

Affiliations

Stefano Mazzanti: Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces
Bogdan Kurpil: Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces
Bartholomäus Pieber: Department of Biomolecular Systems, Max Planck Institute of Colloids and Interfaces
Markus Antonietti: Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces
Aleksandr Savateev: Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces

DOI: https://doi.org/10.1038/s41467-020-15131-0
Journal volume & issue: Vol. 11, no. 1
pp. 1 – 8

Abstract

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Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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