Acta Crystallographica Section E (Sep 2011)

3-{1-[2-(2-Chlorophenyl)hydrazinylidene]-2,2,2-trifluoroethyl}-7-diethylamino-2H-chromen-2-one

  • Hao Chen,
  • Li Cai,
  • Chaochao Yu,
  • Hongqi Li

DOI
https://doi.org/10.1107/S1600536811031916
Journal volume & issue
Vol. 67, no. 9
pp. o2344 – o2344

Abstract

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The title compound, C21H19ClF3N3O2, has a structure related to other coumarin derivatives that have been used as fluorescent probes of metal ions. The dihedral angle between the coumarin ring system and the chlorobenzene ring is 42.99 (9)°. Intramolecular hydrogen bonding occurs via N—H...O and N—H...Cl interactions, generating S(7) and S(5) rings, respectively. The crystal packing is stabilized by weak C—H...O hydrogen bonds.