Battery waste-derived magnetic Fe–Mn–Zn/C composites as an electro-Fenton-like catalyst for the degradation of sodium dodecyl sulfate surfactant

Abstract

A batch-scale electro-Fenton (EF) process was performed using graphite anode and waste battery-based Fe -Mn -Zn/C electrocatalyst coated on low-cost graphite felt cathode. The effectiveness of the EF's performance was evident with around 83.9 + 4.1% removal of 20 mg/L of sodium-dodecyl sulfate surfactant (SDS) at an optimum current density (CD) of 5.0 mA/cm2, Na2SO4 of 0.05 M, initial pH of 7.2, and electrolysis time of 180 min. Moreover, nearly 1.78-fold more removal of SDS was achieved in EF than in the electro-oxidation process operated without any catalyst. The operating cost of 0.35 $ of per m3 per order was needed to treat SDS wastewater. The remediation of SDS follows pseudo-first-order kinetics with a rate constant of 0.0095 min−1. Additionally, 90.3 + 2.1% of SDS and 57 + 2.6% of total organic carbon (TOC) removal was attained during 240 min of treatment time in secondary treated real wastewater; hence, additional 60 min of treatment time is required for effectively treating real wastewater than synthetic wastewater. Thus, EF is effective with battery waste-derived magnetic catalyst for treating wastewater containing SDS, which can lead to achieving sustainable environmental goals. HIGHLIGHTS The current work demonstrates a waste-to-treat-waste approach.; Magnetic Fe–Mn–Zn/C catalyst derived from battery waste was used in electro-Fenton.; Efficacious degradation of surfactant was obtained with a battery waste catalyst.; The kinetics of removal obtained a pseudo-first-order kinetic model.; Lauric acid was formed during sodium dodecyl sulfate degradation.;

Keywords

• battery waste
• electro-fenton
• surfactant
• waste management
• wastewater treatment