Sulfuric Acid Granulation of Copper—Nickel Ore Tailings: Leaching of Copper and Nickel in the Presence of Sulfide Oxidation Activators

Abstract

A laboratory scale study was conducted, aimed at finding an effective method for processing fine concentration tailings of copper-nickel ores. A sulfuric acid tailing granulation process followed by subsequent heap leaching of granules is proposed. Various methods of preparation and storage of the granular material are discussed. A solution of sulfuric acid was used as a binder. It was found that the addition of an oxidizing agent (Fe3+ and NO2−) when irrigating the granules had an effect on the recovery of metals. Changes in the recovery performance of non-ferrous metals into solution were studied under subsequent heap leaching of the material during a period of positive temperatures. The role of nitrogen compounds, in particular, nitrous acid, on the recovery of metals into solution after the preliminary storage of granules at below 0 °C temperatures is also discussed.

Keywords

• concentration tailings
• sulfuric acid granulation
• ferric iron
• nitrite ion
• heap leaching
• temperature below 0 °C