Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V)

Abstract

In the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C—H...O interactions occur. The molecules are connected by intermolecular N—H...O, N—H...N and C—H...O hydrogen-bonding interactions and C—H...π stacking interactions, forming a three-dimensional supramolecular framework