Acta Crystallographica Section E (Nov 2011)

Bis(μ-diethylphosphido-κ2P:P)bis[bis(2,4,6-trimethylphenyl)indium(III)]

  • Glen G. Briand,
  • Andreas Decken,
  • Dane A. Knackstedt,
  • Caleb D. Martin

DOI
https://doi.org/10.1107/S1600536811042668
Journal volume & issue
Vol. 67, no. 11
pp. m1578 – m1578

Abstract

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The title compound, [In2(C9H11)4(C4H10P)2], contains a centrosymmetric In2P2 core with short intermolecular In—P bonds. This core has acute P—In—P and obtuse In—P—In bond angles compared with other [R2InPR′2]2 analogues, due to the presence of the bulky aromatic substituents on the In atom and the non-sterically demanding ethyl substituents on the P atom.