Acta Crystallographica Section E (May 2008)

4-[(E)-Phenyliminomethyl]benzonitrile

  • Asif Hanif Ch,
  • Mushtaq Ahmed,
  • Muhammad Akhtar,
  • M. Nawaz Tahir,
  • Mmuhammad Akram Kashmiri

DOI
https://doi.org/10.1107/S1600536808008672
Journal volume & issue
Vol. 64, no. 5
pp. o790 – o790

Abstract

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In the molecule of the title compound, C14H10N2, the two aromatic rings are oriented at a dihedral angle of 32.22 (6)°. In the crystal structure, intermolecular C—H...N hydrogen bonds link the molecules into centrosymmetric R22(10) dimers. A weak π–π interaction between the cyanobenzene rings, with a centroid–centroid distance of 3.8447 (3) Å, further stabilizes the crystal structure. There is also a C—H...π interaction between the aniline ring and a CH group of the cyanobenzene ring.