Effects of Different Inhibitors on the Corrosion Mitigation of Steel Rebar Immersed in NaCl-Contaminated Concrete Pore Solution

Abstract

The corrosion of steel rebar embedded in concrete under marine conditions is a major global concern. Therefore, it needs a proper corrosion mitigation method. Various types of corrosion inhibitors are used to mitigate the corrosion of steel rebar in chloride-contaminated concrete; however, selecting the appropriate inhibitor and determining its optimal concentration remains a concern. Therefore, in the present study, three types of inhibitors—calcium nitrite (CN: Ca(NO2)2), N,N′-dimethyl ethanol amine (DMEA: (CH3)2NCH2CH2OH), and L-arginine (LA: C6H14N4O2) in three different concentrations, i.e., 0.3, 0.6 and 1.2 M—were compared with a control (without inhibitor, i.e., blank) sample to determine the optimum concentration of the inhibitor for corrosion resistance performance evaluation of reinforcement bars immersed in 0.3 M NaCl-contaminated concrete pore (NCCP) solution for various durations. The corrosion resistance properties were assessed using open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) with immersion duration, and potentiodynamic polarization (PDP) after 168 h of exposure. The results showed that the CN inhibitor performed exceptionally well (corrosion inhibition efficiency greater than 97%) in terms of corrosion resistance. However, due to its hazardous nature and its ban in the U.S. and European Union, CN cannot be used in construction. In comparison, while DMEA showed some effectiveness, LA performed better and is also eco-friendly. The corrosion resistance efficiency of samples containing 0.6 M LA remains above 97% even after 168 h of immersion in the NCCP solution. This efficiency is consistent throughout the entire immersion period, from 1 h to 168 h. Therefore, it is recommended that LA be used as a corrosion inhibitor for steel reinforcement bars instead of CN, particularly in chloride-contaminated concrete, as it is both effective and safer than CN.

Keywords

• steel
• corrosion
• inhibitor
• open circuit potential (OCP)
• electrochemical impedance spectroscopy (EIS)
• potentiodynamic polarization (PDP)