Phosphorus/Phosphide‐Based Materials for Alkali Metal‐Ion Batteries

Fangzheng Chen; Jie Xu; Shanying Wang; Yaohui Lv; Yang Li; Xiang Chen; Ailin Xia; Yongtao Li; Junxiong Wu; Lianbo Ma

doi:10.1002/advs.202200740

Advanced Science (Jun 2022)

Phosphorus/Phosphide‐Based Materials for Alkali Metal‐Ion Batteries

Fangzheng Chen,
Jie Xu,
Shanying Wang,
Yaohui Lv,
Yang Li,
Xiang Chen,
Ailin Xia,
Yongtao Li,
Junxiong Wu,
Lianbo Ma

Affiliations

Fangzheng Chen: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Jie Xu: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Shanying Wang: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Yaohui Lv: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Yang Li: Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology (HKUST) Clear Water Bay Hong Kong 999077 China
Xiang Chen: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Ailin Xia: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Yongtao Li: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China
Junxiong Wu: College of Environmental Science and Engineering Fujian Normal University Fuzhou Fujian 350000 China
Lianbo Ma: Low‐Carbon New Materials Research Center Low‐Carbon Research Institute, School of Materials Science and Engineering Anhui University of Technology Maanshan 243002 China

DOI: https://doi.org/10.1002/advs.202200740
Journal volume & issue: Vol. 9, no. 17
pp. n/a – n/a

Abstract

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Abstract Phosphorus‐ and phosphide‐based materials with remarkable physicochemical properties and low costs have attracted significant attention as the anodes of alkali metal (e.g., Li, Na, K, Mg, Ca)‐ion batteries (AIBs). However, the low electrical conductivity and large volume expansion of these materials during electrochemical reactions inhibit their practical applications. To solve these problems, various promising solutions have been explored and utilized. In this review, the recent progress in AIBs using phosphorus‐ and phosphide‐based materials is summarized. Thereafter, the in‐depth working principles of diverse AIBs are discussed and predicted. Representative works with design concepts, construction approaches, engineering strategies, special functions, and electrochemical results are listed and discussed in detail. Finally, the existing challenges and issues are concluded and analyzed, and future perspectives and research directions are given. This review can provide new guidance for the future design and practical applications of phosphorus‐ and phosphide‐based materials used in AIBs.

Published in Advanced Science

ISSN: 2198-3844 (Online)
Publisher: Wiley
Country of publisher: Germany
LCC subjects: Science
Website: https://onlinelibrary.wiley.com/journal/21983844

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