A simple method to prepare anion exchange membrane by PVA/EVOH/MIDA for acid recovery by diffusion dialysis

Abstract

Given the substantial environmental pollution from industrial expansion, environmental protection has become particularly important. Nowadays, anion exchange membranes (AEMs) are widely used in wastewater treatment. With the use of polyvinyl alcohol (PVA), ethylene-vinyl alcohol (EVOH) copolymer, and methyl iminodiacetic acid (MIDA), a series of cross-linked AEMs were successfully prepared using the solvent casting technique, and the network structure was formed in the membranes due to the cross-linking reaction between PVA/EVOH and MIDA. Fourier transform infrared spectrometer, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy were used to analyze the prepared membranes. At the same time, its comprehensive properties which include water uptake, linear expansion rate, ion exchange capacity, thermal stability, chemical stability, and mechanical stability were thoroughly researched. In addition, diffusion dialysis performance in practical applications was also studied in detail. The acid dialysis coefficient (UH+) ranged from 10.2 to 35.6 × 10−3 m/h. Separation factor (S) value ranged from 25 to 38, which were all larger than that of the commercial membrane DF-120 (UH+: 8.5 × 10−3 m/h, S: 18.5). The prepared membranes had potential application value in acid recovery. HIGHLIGHTS The preparation method of the membranes is simple.; The membrane is based on PVA/EVOH/MIDA.; The raw materials are cheap and easy to obtain.; The acid recovery performance is excellent by diffusion dialysis.; The prepared membranes had potential application value in acid recovery.;

Keywords

• acid recovery
• anion exchange membrane
• diffusion dialysis
• ethylene-vinyl alcohol copolymer
• methyl iminodiacetic acid
• polyvinyl alcohol