Spin-Crossover in Iron(II) Complexes of N,N′-Disubstituted 2,6-Bis(Pyrazol-3-yl)Pyridines: An Effect of a Distal Substituent in the 2,6-Dibromophenyl Group

Abstract

A series of new bis(pyrazol-3-yl)pyridines (LR) N,N′-disubstituted by 4-functionalized 2,6-dibromophenyl groups have been synthesized to study the effect of a distal substituent on the spin-crossover (SCO) behaviour of the iron(II) complexes [Fe(LR)2](ClO4)2 by variable-temperature magnetometry, NMR spectroscopy, and X-ray diffraction. The SCO-assisting tendency of the substituents with different electronic and steric properties (i.e., the bromine atom and the methyl group) in the para-position of the 2,6-dibromophenyl group is discussed. Together with earlier reported SCO-active iron(II) complexes with N,N′-disubstituted bis(pyrazol-3-yl)pyridines, these new complexes open the way for this family of SCO compounds to emerge as an effective ‘tool’ in revealing structure–function relations, a prerequisite for successful molecular design of switchable materials for future breakthrough applications in sensing, switching, and memory devices.

Keywords

• distal substituent
• iron(II) complexes
• molecular design
• paramagnetic NMR spectroscopy
• spin-crossover
• X-ray diffraction