Hydrothermal Synthesis of Boron-Doped Graphene for High-Performance Zinc-Ion Hybrid Capacitor Using Aloe Vera Gel Electrolyte

Abstract

The great interest in developing emerging zinc-ion capacitors (ZIC) for energy storage applications is due to their inexpensiveness and the future necessity for hybrid electrical energy storage devices. The Zn-ion hybrid capacitor device was assembled using boron (B)-doped reduced graphene oxide (B-RGO) material, which acts as the cathode, and pure zinc metal as an anode. This research work aims to study the influence of B-doped reduced graphene oxide (B-RGO) with Aloe vera gel as an electrolyte. The reduced graphene oxide (RGO) and B-RGO electrode active materials were confirmed through X-ray diffraction (XRD), RAMAN, Fourier transformation infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM) and field emission-transmission electron microscopy (FE-TEM) analysis. The surface morphological images reveal that a few-layered nanostructure B-RGO was used in the Zn-ion hybrid capacitor device. The electrochemical performance of the Zn-ion hybrid capacitor was evaluated through cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) measurements, with a wide active potential range of 0–2 V versus Zn/Zn+. The mixture composition of Aloe vera extract and 1M ZnSO4 electrolyte generated a stable voltage and exhibited good capacitive behavior. The fabricated ZIC coin cell device with the Aloe vera gel semi-gel electrolyte containing ZnSO4 demonstrated improved Zn+ ionic exchange and storage efficiency. Moreover, the B-RGO electrode active material exhibited excellent cycle stability. The simple one-step electrochemical technique is the most suitable process for boron doping into graphene nanosheets for future energy storage applications.

Keywords

• zinc-ion capacitor
• Aloe vera
• gel electrolyte
• heteroatom
• graphene