Nature Communications (Jan 2023)
COx hydrogenation to methanol and other hydrocarbons under mild conditions with Mo3S4@ZSM-5
- Gui Liu,
- Pengfei Liu,
- Deming Meng,
- Taotao Zhao,
- Xiaofeng Qian,
- Qiang He,
- Xuefeng Guo,
- Jizhen Qi,
- Luming Peng,
- Nianhua Xue,
- Yan Zhu,
- Jingyuan Ma,
- Qiang Wang,
- Xi Liu,
- Liwei Chen,
- Weiping Ding
Affiliations
- Gui Liu
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Pengfei Liu
- Department of Applied Chemistry, School of Chemistry and Molecular Engineering, Nanjing Tech University
- Deming Meng
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Taotao Zhao
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Xiaofeng Qian
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Qiang He
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Xuefeng Guo
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Jizhen Qi
- i-Lab, CAS Centre for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences
- Luming Peng
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Nianhua Xue
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Yan Zhu
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- Jingyuan Ma
- Shanghai Synchrotron Radiation Facility, Pudong New District
- Qiang Wang
- Department of Applied Chemistry, School of Chemistry and Molecular Engineering, Nanjing Tech University
- Xi Liu
- School of Chemistry and Chemical, In-situ Centre for Physical Sciences, Frontiers Science Centre for Transformative Molecules, Shanghai Jiao Tong University
- Liwei Chen
- i-Lab, CAS Centre for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences
- Weiping Ding
- Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
- DOI
- https://doi.org/10.1038/s41467-023-36259-9
- Journal volume & issue
-
Vol. 14,
no. 1
pp. 1 – 11
Abstract
A series of materials containing Mo-S clusters confined in zeolitic cages of ZSM-5 are reported and shown to be efficient for CO2 or CO hydrogenation with >98% selectivity to methanol, stable over 1000 h, or C2 and C3 hydrocarbons, stable over 100 h.
