APL Materials (Jan 2015)

Structural evolution in Ti-Cu-Ni metallic glasses during heating

  • P. Gargarella,
  • S. Pauly,
  • M. Stoica,
  • G. Vaughan,
  • C. R. M. Afonso,
  • U. Kühn,
  • J. Eckert

DOI
https://doi.org/10.1063/1.4905287
Journal volume & issue
Vol. 3, no. 1
pp. 016101 – 016101-6

Abstract

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The structural evolution of Ti50Cu43Ni7 and Ti55Cu35Ni10 metallic glasses during heating was investigated by in-situ synchrotron X-ray diffraction. The width of the most intense diffraction maximum of the glassy phase decreases slightly during relaxation below the glass transition temperature. Significant structural changes only occur above the glass transition manifesting in a change in the respective peak positions. At even higher temperatures, nanocrystals of the shape memory B2-Ti(Cu,Ni) phase precipitate, and their small size hampers the occurrence of a martensitic transformation.