Heliyon (Jun 2024)

Towards dark current suppression in metallic photocathodes by selected-area oxidation

  • C. Benjamin,
  • S.D. Seddon,
  • M. Walker,
  • L.B. Jones,
  • T.C.Q. Noakes,
  • G.R. Bell

Journal volume & issue
Vol. 10, no. 11
p. e31461

Abstract

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Oxide-free surfaces of polycrystalline Cu are prepared using acetic acid etching after chemical-mechanical polishing. UV ozone treatment is shown to increase the work function of the cleaned Cu by up to 0.5 eV. There is also a large reduction in quantum efficiency at 265 nm. Cu sheet can be easily masked from ozone exposure by Si or glass, meaning that selected-area oxi-dation is possible. Oxygen plasma treatment has a similar effect to the UV ozone but is more difficult to mask. There is no increase in surface roughness after oxidation, meaning that the larger work function could significantly re-duce dark current in accelerator photocathodes without affecting the desired photoemission region.

Keywords