Acta Crystallographica Section E (Aug 2012)

trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN3)copper(II)

  • Fatih Şen,
  • Ramazan Şahin,
  • Ömer Andaç,
  • Murat Taş

DOI
https://doi.org/10.1107/S1600536812030607
Journal volume & issue
Vol. 68, no. 8
pp. m1045 – m1045

Abstract

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In the title compound, [Cu(NO3)2(C5H6N2)4], the CuII ion is located on an inversion centre. It features a Jahn–Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6):0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C—H...O and C—H...π interactions.