The Impact of the Composition Effect on Ferromagnetic Properties of Tb₂Co₂Ga

Abstract

The ferromagnetic properties of Tb2Co2Ga, crystallizing into an orthorhombic W2CoB2-type structure, were investigated by preparing 11 polycrystalline samples with different starting atomic compositions. We found that Tb2Co2Ga possesses a homogeneity range in the ternary phase diagram. The Curie temperature TC is sensitive to the atomic composition and ranges rather widely, i.e., from 75 to 145 K. For the samples with a TC above 90 K, the nearest Tb−Tb and the Tb−Co distances would be important factors deciding TC, considering the RKKY interaction through the hybridization between Tb and Co atoms. An anisotropic change of two kinds of Co−Tb−Co angles in the octahedron formed by two Tb and four Co atoms occurs in the samples with a TC lower than 90 K. Such a change of octahedral parameters seems to be related to a difference of shapes in the ac magnetization anomaly at TC between the samples in the lowest TC (~ 75 K) group and those in the other groups.

Keywords

• ferromagnetism
• w2cob2-type structure
• composition effect
• magnetic measurements
• lattice parameters