Enhancing Cu<sup>2+</sup> Ion Removal: An Innovative Approach Utilizing Modified Frankincense Gum Combined with Multiwalled Carbon Tubes and Iron Oxide Nanoparticles as Adsorbent

Mushtaq Hussain; Syed Sulaiman Hussaini; Mohammad Shariq; Hanan Alzahrani; Arafa A. Alholaisi; Samar H. Alharbi; Sirajah A. Alsharif; Wafa Al-Gethami; Syed Kashif Ali; Abdel-Nasser M. A. Alaghaz; Mohd Asim Siddiqui; Kondaiah Seku

doi:10.3390/molecules28114494

Molecules (Jun 2023)

Enhancing Cu<sup>2+</sup> Ion Removal: An Innovative Approach Utilizing Modified Frankincense Gum Combined with Multiwalled Carbon Tubes and Iron Oxide Nanoparticles as Adsorbent

Mushtaq Hussain,
Syed Sulaiman Hussaini,
Mohammad Shariq,
Hanan Alzahrani,
Arafa A. Alholaisi,
Samar H. Alharbi,
Sirajah A. Alsharif,
Wafa Al-Gethami,
Syed Kashif Ali,
Abdel-Nasser M. A. Alaghaz,
Mohd Asim Siddiqui,
Kondaiah Seku

Affiliations

Mushtaq Hussain: Engineering Department, College of Engineering and Technology, University of Technology and Applied Sciences, Shinas 324, Oman
Syed Sulaiman Hussaini: Engineering Department, College of Engineering and Technology, University of Technology and Applied Sciences, Shinas 324, Oman
Mohammad Shariq: Department of Physics, College of Science, Jazan University, Jazan 45142, Saudi Arabia
Hanan Alzahrani: Department of Physics, College of Science, Jazan University, Jazan 45142, Saudi Arabia
Arafa A. Alholaisi: Department of Physics, Al-Qunfudah University College, Umm Al-Qura University, Makkah 24382, Saudi Arabia
Samar H. Alharbi: Department of Physics, Al-Qunfudah University College, Umm Al-Qura University, Makkah 24382, Saudi Arabia
Sirajah A. Alsharif: Department of Physics, Al-Qunfudah University College, Umm Al-Qura University, Makkah 24382, Saudi Arabia
Wafa Al-Gethami: Chemistry Department, Faculty of Science, Taif University, Al-Hawiah, Taif City P.O. Box 11099, Saudi Arabia
Syed Kashif Ali: Department of Chemistry, College of Science, Jazan University, Jazan 45142, Saudi Arabia
Abdel-Nasser M. A. Alaghaz: Department of Chemistry, College of Science, Jazan University, Jazan 45142, Saudi Arabia
Mohd Asim Siddiqui: Engineering Department, College of Engineering and Technology, University of Technology and Applied Sciences, Shinas 324, Oman
Kondaiah Seku: Engineering Department, College of Engineering and Technology, University of Technology and Applied Sciences, Shinas 324, Oman

DOI: https://doi.org/10.3390/molecules28114494
Journal volume & issue: Vol. 28, no. 11
p. 4494

Abstract

Read online

Aquatic pollution, which includes organic debris and heavy metals, is a severe issue for living things. Copper pollution is hazardous to people, and there is a need to develop effective methods for eliminating it from the environment. To address this issue, a novel adsorbent composed of frankincense-modified multi-walled carbon nanotubes (Fr-MMWCNTs) and Fe3O4 [Fr-MWCNT-Fe3O4] was created and subjected to characterization. Batch adsorption tests showed that Fr-MWCNT-Fe3O4 had a maximum adsorption capacity of 250 mg/g at 308 K and could efficiently remove Cu2+ ions over a pH range of 6 to 8. The adsorption process followed the pseudo-second-order and Langmuir models, and its thermodynamics were identified as endothermic. Functional groups on the surface of modified MWCNTs improved their adsorption capacity, and a rise in temperature increased the adsorption efficiency. These results highlight the Fr-MWCNT-Fe3O4 composites’ potential as an efficient adsorbent for removing Cu2+ ions from untreated natural water sources.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

About the journal

Abstract

Keywords