Effect of montmorillonite on PEBAX® 1074-based mixed matrix membranes to be used in humidifiers in proton exchange membrane fuel cells

Abstract

To meet the increasing requirements of membrane humidification in proton exchange membrane fuel cells (PEMFCs), a series of montmorillonite (MMT)/PEBAX® 1074 mixed matrix membranes (MMMs) were fabricated using the solvent casting method. Pristine MMT and poly(oxyalkylene)amine (APOP)-modified MMT were added as the filler. Using the XRD, FT-IR, SEM, and TEM, the morphology and chemical structure of MMT during modification were investigated. Using the tests of water vapor permeability, air permeability, water contact angle, and crystallinity, the effects of montmorillonite on membrane properties were investigated. The results showed that surface hydrophilicity and crystallinity of MMMs increased as the MMT content increases, which leads to higher vapor permeability and selectivity than the pure PEBAX® 1074 membrane. After modification, APOP-MMT/PEBAX® 1074 MMMs showed better performance in vapor permeability and vapor/air selectivity. The best selectivity was 1.7 × 105, which is three times higher than that of pure PEBAX® 1074 membrane.

Keywords

• mixed matrix membrane
• membrane humidifier
• vapor permeability
• pebax® 1074
• montmorillonite