Nanomaterials (Aug 2021)

NOx Storage on BaTi<sub>0.8</sub>Cu<sub>0.2</sub>O<sub>3</sub> Perovskite Catalysts: Addressing a Feasible Mechanism

  • Vicente Albaladejo-Fuentes,
  • María-Salvadora Sánchez-Adsuar,
  • James A. Anderson,
  • María-José Illán-Gómez

DOI
https://doi.org/10.3390/nano11082133
Journal volume & issue
Vol. 11, no. 8
p. 2133

Abstract

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The NOx storage mechanism on BaTi0.8Cu0.2O3 catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage–regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba2TiO4 plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O2 and NO/N2 show that nitrites and nitrates are formed on the perovskite during the NOx storage process. Thus, it seems that, as for model NSR catalysts, the NOx storage on BaTi0.8Cu0.2O3 catalyst takes place by both “nitrite” and “nitrate” routes, with the main pathway being highly dependent on the temperature and the time on stream: (i) at T 350 °C, the catalyst activity for NO oxidation promotes NO2 generation and the nitrate formation.

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