(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate

Abstract

In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the AgI atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H...O hydrogen bonds, generating tetramers (two cations and two anions), which feature R22(8) and R44(8) loops. The cations are linked by weak C—H...π interactions, generating a three-dimensional network.

Keywords

• N-phenylthiourea
• triphenylphosphane
• silver(I)nitrate
• crystal structure