Saline Diffusion Modeling for Sodium Chloride Aqueous Solutions: Freezing for Desalination Purposes

Abstract

Given the high human demand for freshwater and its consequent scarcity, desalination processing seems to be a key solution, given the vast amount of seawater on the planet. Currently, desalination plants provide about 95 million m3/day freshwater in 177 countries worldwide. However, desalination is an energy-intensive, demanding technique that generally uses fossil fuels and contributes to global warming via greenhouse gas emissions. Freezing/melting desalination (F/M) uses about 70% less thermal energy than the boiling process. Unfortunately, this technique is rarely used, mainly because of salt separation problems at low temperatures close to 0 °C. Most models have determined their results assuming a saline concentration value of the retained liquid; however, there is a significant disagreement in this value. This study proposes a unidimensional model based on thermal and mass diffusion evolution. The model predicts the successful separation of salt-free ice to avoid salt diffusion before encapsulation; the process depends on temperature, saline gradients, and time. The calculations in this paper are based on the salt concentration in the liquid-solid interface, which has been extensively studied, achieving an accurate performance of the proposed model.

Keywords

• freezing/melting desalination
• aqueous sodium chloride solutions
• theoretical diffusive models