Chemical Engineering Transactions (Oct 2024)

Modelling Fire Response of Cryogenic Liquid Hydrogen Tanks Equipped with Multilayer Insulation (MLI) Systems

  • Davide Camplese,
  • Giordano Emrys Scarponi,
  • Robert Eberwein,
  • Aliasghar Hajharir,
  • Frank Otremba,
  • Valerio Cozzani

Journal volume & issue
Vol. 111

Abstract

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In the context of the growing global interest in hydrogen-based green energy, cryogenic tanks equipped with multi-layer insulation (MLI) are emerging as a leading solution for storing hydrogen in vehicles. The integrity of these systems might be threatened during fire exposure. This can trigger the degradation of the MLI materials and induce rapid pressurization of the tank with a high risk of catastrophic failure. In this work, a novel lumped model to simulate the thermal response of MLI-equipped cryogenic liquid hydrogen tanks is presented. The model integrates the accurate database “Coolprop” for hydrogen thermodynamic properties and sub-models for detailed simulation of MLI degradation, providing a realistic simulation of the experimental data obtained under normal operating conditions. The application of the model to several case studies considering different numbers of MLI layers and tank geometries demonstrates that aluminum-based MLI offers scarce protection in case of exposure to a hydrocarbon poolfire.