Ultrasonic Cavitation Erosion Behavior of CoCr_xFeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding

Abstract

CoCrxFeMnNi (x represents the atomic percentage of Cr element, x = 20, 25, 30, and 35, denoted as Cr20, Cr25, Cr30, and Cr35 alloys) high-entropy alloy (HEA) coatings were cladded by plasma arc on the surface of 0Cr13Ni5Mo steel. The effects of Cr elements on the cavitation erosion mechanisms were studied by comparing the differences of microstructure, microhardness, cavitation erosion volume loss (CVL), cavitation erosion volume loss rate (CER), and eroded surface morphologies between the coatings. As the Cr content increased, the microhardness of the coatings increased continuously, and the microstructure transformed into fine dendrites. The microhardnesses of Cr20, Cr25, Cr30, and Cr35 were 223.9 HV, 250.5 HV, 265.2 HV, and 333.7 HV, respectively. With structural change, the slip pattern shifted from uniform distribution to distribution along the grain boundary, increasing slip resistance. Additionally, strain hardening capacity increased with reduced stacking fault energy (SFE). The resistance to cavitation erosion (CR) of the HEA increased with the increase in Cr content. The CVL of 20 h cavitation erosion of Cr35 coating was only 26.84% of that of 0Cr13Ni5Mo steel, and the peak CER was only 28.75% of that of 0Cr13Ni5Mo steel. The fracture damage mechanisms of the four HEA coatings were an obvious lamellar structure and fibrous fracture.

Keywords

• high-entropic alloys
• plasma cladding
• cavitation
• corrosion
• stacking fault energy