Magnetochemistry (Aug 2021)

Self-Assembly and Magnetic Order of Bi-Molecular 2D Spin Lattices of M(II,III) Phthalocyanines on Au(111)

  • Miloš Baljozović,
  • Xunshan Liu,
  • Olha Popova,
  • Jan Girovsky,
  • Jan Nowakowski,
  • Harald Rossmann,
  • Thomas Nijs,
  • Mina Moradi,
  • S. Fatemeh Mousavi,
  • Nicholas C. Plumb,
  • Milan Radović,
  • Nirmalya Ballav,
  • Jan Dreiser,
  • Silvio Decurtins,
  • Igor A. Pašti,
  • Natalia V. Skorodumova,
  • Shi-Xia Liu,
  • Thomas A. Jung

DOI
https://doi.org/10.3390/magnetochemistry7080119
Journal volume & issue
Vol. 7, no. 8
p. 119

Abstract

Read online

Single layer low-dimensional materials are presently of emerging interest, including in the context of magnetism. In the present report, on-surface supramolecular architecturing was further developed and employed to create surface supported two-dimensional binary spin arrays on atomically clean non-magnetic Au(111). By chemical programming of the modules, different checkerboards were produced combining phthalocyanines containing metals of different oxidation and spin states, diamagnetic zinc, and a metal-free ‘spacer’. In an in-depth, spectro-microscopy and theoretical account, we correlate the structure and the magnetic properties of these tunable systems and discuss the emergence of 2D Kondo magnetism from the spin-bearing components and via the physico-chemical bonding to the underlying substrate. The contributions of the individual elements, as well as the role of the electronic surface state in the bottom substrate, are discussed, also looking towards further in-depth investigations.

Keywords