Acta Crystallographica Section E (Feb 2013)

6-Bromo-1-methyl-4-[2-(1-phenylethylidene)hydrazinylidene]-3,4-dihydro-1H-2λ6,1-benzothiazine-2,2-dione

  • Muhammad Shafiq,
  • M. Nawaz Tahir,
  • William T. A. Harrison,
  • Iftikhar Hussain Bukhari,
  • Islam Ullah Khan

DOI
https://doi.org/10.1107/S1600536812051380
Journal volume & issue
Vol. 69, no. 2
pp. o164 – o164

Abstract

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In the title compound, C17H16BrN3O2S, the dihedral angle between the aromatic rings is 1.24 (15)° and the C=N—N=C torsion angle is 167.7 (3)°. The conformation of the thiazine ring is an envelope, with the S atom displaced by 0.805 (3) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.027 Å). In the crystal, C—H...O interactions link the molecules into C(10) [010] chains. A weak C—H...π interaction is also observed.