Application of Magnetic Nanocomposites in Water Treatment: Core–Shell Fe₃O₄ Material for Efficient Adsorption of Cr(VI)

Abstract

Since ferric tetroxide (Fe3O4) has strong magnetic properties, coating amorphous silica (SiO2) with Fe3O4 nanoparticles can protect the magnetic Fe3O4 particles and form a new magnetic adsorbent with a core–shell structure and small pore size, the strong magnetic properties of which can efficiently solve the problem of the difficult separation and recovery of heavy metals from wastewater affecting present-day adsorption techniques. In this paper, SiO2-coated nanoscale Fe3O4 particles were prepared using a modified sol–gel method for the adsorption and removal of Cr(VI) at lower pollution concentrations. The adsorbent was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and a magnetic vibration sample magnetometer (VSM), and its adsorption performance was systematically investigated in terms of initial concentration, pH, and temperature. The experiments showed that the adsorption effect was optimal when the initial solution Cr(VI) was 40 mg/L. The adsorption capacity increased with a decrease in the initial solution’s pH and decreased with an increase in temperature. Furthermore, the adsorption capacity of Cr(VI) at low concentrations was much higher than that of other conventional adsorbents, the calculated unit adsorption capacity reached 13.609 mg·g−1, and the removal rate reached 64.8%. In addition, the strong magnetic nanocomposite (MS) had excellent recoverability, could achieve desorption via alkaline washing, and retained about 75% of the initial adsorption capacity after six cycles.

Keywords

• hexavalent chromium removal
• Fe₃O₄ particles
• SiO₂ coating
• core–shell structure
• strong magnetic