Tribological Properties of Protic Ionic Liquid as an Additive in Aqueous Glycerol Solution for Ruby-Bearing Steel Tribo-Contact

Abstract

Owing to their low cost and environmentally friendly nature, water-based lubricants have benefits over oil-based ones. However, the appropriate additive package is indispensable in improving its tribological properties. In the current study, we have investigated the friction and wear reduction ability of bis(2-hydroxyethyl) ammonium oleate protic ionic liquid (PIL) in a glycerol aqueous lubricating fluid. The tribo-tests were performed using a ruby–steel friction pair acting in reciprocation mode. The coefficient of friction and wear were the main characteristics of the evaluation. Analysis of the physical properties of the investigated lubricating samples and worn surface analysis were performed to reveal a more detailed picture. The study shows that the investigated PIL can significantly reduce friction and wear. The most suitable concentration of PIL was 0.5%, where friction and wear were reduced 2.6 and 15.8 times, respectively. Using the investigated PIL facilitates a sliding coefficient of friction as low as 0.039. It was hypothesized that the formation of the adsorption layer and metal soap was responsible for this. Further studies could be directed toward higher load and speed applications.

Keywords

• ionic liquid
• lubrication
• adsorption
• friction
• wear
• metal soap