Catalysis Communications (Feb 2022)

Rationally designed Sb2S3/PDI composites with enhanced visible light photoactivity

  • Jin-Ge Hao,
  • Hui-Qi Chen,
  • Lei Xie,
  • Ze-Xiang Li,
  • Jia-Lin Zhang,
  • Wei-Ya Huang,
  • Tao Deng,
  • Kang-Qiang Lu,
  • Kai Yang

Journal volume & issue
Vol. 162
p. 106368

Abstract

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Constructing organic-inorganic semiconductor heterojunctions is an efficient way to inhibit the recombination of photogenerated charge carriers and enhance photocatalytic performance of semiconductor. Herein, a novel heterojunction antimony sulfide-perylene diimides (Sb2S3-PDI) heterojunction has been fabricated through a facile hydrothermal method. Compared with bare Sb2S3 and PDI, the Sb2S3-PDI hybrid has showed significantly superior activity in photocatalytic reduction of Cr (VI). The superior photocatalytic performance of Sb2S3-PDI hybrid is due to the formation of type-I heterojunction, which leads to a more efficient separation and migration of photogenerated electron-hole pairs. This work is expected to promote continued interest in the construction of organic-inorganic semiconductor composites with enhanced photocatalytic performance.

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