Química Nova (Jul 2014)

Solo contaminado com cádmio: extratibilidade do metal e cinética química de degradação da matéria orgânica de torta de filtro

  • Lucia Pittol Firme,
  • Felipe Carlos Alvarez Villanueva,
  • Antonio Arnaldo Rodella

DOI
https://doi.org/10.5935/0100-4042.20140173
Journal volume & issue
Vol. 37, no. 6
pp. 956 – 963

Abstract

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The chemical kinetics of sugarcane filter cake (FC) organic matter degradation at rates (0, 40, 80, and 120 t ha-1) in non-contaminated and different degrees of cadmium-contaminated Oxisol (0.19, 28, 56, 112 and 200 mg Cd kg-1) and DTPA-extractable Cd was studied. FC degradation was determined by quantifying CO2 emitted from soil samples during 72 days of incubation. DTPA-extractable Cd was performed after the incubation period. FC degradation was described by a two-stage equation of chemical kinetics. FC degradation rates were between 15 and 33%. Total CO2 emitted from FC declined with increasing degree in Cd-contamination and the DTPA-extractable Cd declined with FC rates.

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