[4,4′-Bis(4-fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine] [bis (2-(diphenylphosphino) phenyl) ether] Silver(I) Hexafluorophosphate

Dimitrios Glykos; John C. Plakatouras; Gerasimos Malandrinos

doi:10.3390/M1675

Molbank (Jun 2023)

[4,4′-Bis(4-fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine] [bis (2-(diphenylphosphino) phenyl) ether] Silver(I) Hexafluorophosphate

Dimitrios Glykos,
John C. Plakatouras,
Gerasimos Malandrinos

Affiliations

Dimitrios Glykos: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
John C. Plakatouras: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
Gerasimos Malandrinos: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

DOI: https://doi.org/10.3390/M1675
Journal volume & issue: Vol. 2023, no. 3
p. M1675

Abstract

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A new emissive heteroleptic Ag(I) complex formulated as [AgL(POP)][PF6] (L = 4,4′-bis (4-Fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine, POP= bis (2-(diphenylphosphino) phenyl) ether) was synthesized and characterized in both the solid state (X-ray crystallography) and the solution. The compound is a yellow-green phosphor (λem = 528 nm), with moderate quantum efficiency (ΦPL = 25% in deaerated dichloromethane).

Published in Molbank

ISSN: 1422-8599 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: https://www.mdpi.com/journal/molbank

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