Hierarchical Design of CuO/Nickel–Cobalt–Sulfide Electrode by a Facile Two-Step Potentiostatic Deposition

Abstract

Herein, a scalable electrodeposition strategy is proposed to achieve hierarchical CuO/nickel–cobalt–sulfide (NCS) electrodes using two-step potentiostatic deposition followed by high-temperature calcination. The introduction of CuO provides support for the further deposition of NSC to ensure a high load of active electrode materials, thus generating more abundant active electrochemical sites. Meanwhile, dense deposited NSC nanosheets are connected to each other to form many chambers. Such a hierarchical electrode prompts a smooth and orderly transmission channel for electron transport, and reserves space for possible volume expansion during the electrochemical test process. As a result, the CuO/NCS electrode exhibits superior specific capacitance (Cs) of 4.26 F cm−2 at 20 mA cm−2 and remarkable coulombic efficiency of 96.37%. Furthermore, the cycle stability of the CuO/NCS electrode remains at 83.05% within 5000 cycles. The multistep electrodeposition strategy provides a basis and reference for the rational design of hierarchical electrodes to be applied in the field of energy storage.

Keywords

• electrode material
• transition metal sulfides
• nanosheet
• potentiostatic deposition