Nature Communications (Sep 2022)

Strain-regulated Gibbs free energy enables reversible redox chemistry of chalcogenides for sodium ion batteries

  • Minxia Jiang,
  • Yingjie Hu,
  • Baoguang Mao,
  • Yixin Wang,
  • Zhen Yang,
  • Tao Meng,
  • Xin Wang,
  • Minhua Cao

DOI
https://doi.org/10.1038/s41467-022-33329-2
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 13

Abstract

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Manipulating the redox chemistry of transition metal dichalcogenides still faces challenges. Here the authors report that tensile-strained MoSe2 can pass on the strain to its sodiated product Mo, and thus regulate the Gibbs free energy in the charging process to enable the reversible sodium storage.