E-Journal of Chemistry (Jan 2012)

A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions

  • Li-Hong Huang,
  • Ji-Dong Lou,
  • Changhe Zhang,
  • Fang Lin,
  • Xiao-Nan Zou

DOI
https://doi.org/10.1155/2012/826527
Journal volume & issue
Vol. 9, no. 4
pp. 2141 – 2144

Abstract

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Oxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to using a polar aprotic solvent.