{[(E)-(1,3-Benzodioxol-5-yl)methylidene]amino}thiourea

Abstract

The synthesis and crystallographic analysis of the title compound, C9H9N3O2S, are reported. The compound crystallizes in the monoclinic space group P21/c, revealing characteristic bond lengths and angles typical of thiosemicarbazone groups. The supramolecular organization primarily arises from hydrogen bonding and π–π stacking interactions, leading to distinctive dimeric formations.

Keywords

• crystal structure
• thio-semicarbazone
• three-dimensional network