Mechanical, Corrosion and Wear Characteristics of Cu-Based Composites Reinforced with Zirconium Diboride Consolidated by SPS

Abstract

This study aimed to investigate the physical, mechanical, corrosion, and tribological properties of Cu-based composites with varying zirconium diboride content. The composites were successfully consolidated using spark plasma sintering (SPS) at temperatures of 850 °C and 950 °C and a pressure of 35 MPa. The effect of the ZrB2 content and the sintering temperature on the properties of the Cu-based composites was investigated. Scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and X-ray diffraction were used to analyse microstructure evolution in copper matrix composites. Microhardness tests were used to evaluate mechanical properties. Wear behaviour was evaluated using a ball-on-disc method. Corrosion properties were estimated on electrochemical tests, such as potentiodynamic polarisation. The results demonstrated an enhancement in the density and porosity of the composites as the sintering temperature increased. A uniform dispersion of ZrB2 was observed in the copper matrix for all composites. With an increase in the content of the ZrB2 reinforcement phase, there was an increase in microhardness and an improvement in the wear resistance of the sintered composites. A reduction in densification and corrosion resistance of Cu-based composites was observed with increasing ZrB2 content.

Keywords

• copper matrix composite
• zirconium diboride
• spark plasma sintering
• wear resistance
• corrosion resistance