High-Surface-Area-Activated Carbon Derived from Mango Peels and Seeds Wastes via Microwave-Induced ZnCl₂ Activation for Adsorption of Methylene Blue Dye Molecules: Statistical Optimization and Mechanism

Abstract

In this study, Mango (Mangifera indica) seeds (MS) and peels (MP) seeds mixed fruit wastes were employed as a renewable precursor to synthesize high-surface-area-activated carbon (MSMPAC) by using microwave-induced ZnCl2 activation. Thus, the applicability of MSMPAC was evaluated towards the removal of cationic dye (methylene blue, MB) from an aqueous environment. The key adsorption factors, namely A: MSMPAC dose (0.02–0.1 g), B: pH (4–10), and C: time (5–15 min), were inspected using the desirability function of the Box-Behnken design (BBD). Thus, the adsorption isotherm data were found to correspond well with the Langmuir model with a maximum adsorption capacity of (232.8 mg/g). Moreover, the adsorption kinetics were consistent with both pseudo-first-order and pseudo-second-order models. The spontaneous and endothermic nature of MB adsorption on the MSMPAC surface could be inferred from the negative ∆G° values and positive value of ∆H°, respectively. Various mechanisms namely electrostatic forces, pore filling, π-π stacking, and H-bonding govern MB adsorption by the MSMPAC. This study demonstrates the utility of MS and MP as renewable precursors to produce high-surface area MSMPAC with a potential application towards the removal of cationic organic dyes such as MB.

Keywords

• activated carbon
• Mango wastes
• ZnCl₂ activation
• adsorption mechanism
• methylene blue
• Box-Behnken design