Improving the performance characteristics of gas concrete impregnated with calcium polysulfide

Abstract

Introduction. Impregnation with a solution based on calcium polysulfide showed excellent results in the hydrophobization of concrete, brick and shell rock due to the formation of a water-repellent coating of sulfur nanoparticles on the surface of their pores. This paper presents the data of studying the properties of aerated concrete, widespread in construction practice, which has a widely developed pore system. Materials and methods. The data on the penetration of water into the studied samples of aerated concrete using the methods of visual examination, including electron microscopy, as well as methods for measuring the water absorption and strength of the samples impregnated with a solution based on calcium polysulfide are presented. Results. It is shown that aerated concrete impregnated with calcium polysulfide, despite the developed pore system, acquires pronounced water-repellent properties. It was found that the optimal processing time is 20 minutes, and the increase in the water-repellent properties of aerated concrete depends on the density of the impregnating solution. As a result of impregnation of aerated concrete by immersion in a solution with a density of 1.16 g/cm3, a decrease in 3.7 times occurs, and when treated with a solution with a density of 1.25 g/cm3, it decreases 6.8 times and becomes equal to 6%. For samples processed with the use of vacuum, in the case of processing a solution with a density of 1.16 g/cm3, water absorption decreases by 7.9 times, and when processing with a solution using vacuum, it decreases 19.8 times, while the compressive strength increases by 1.7 once. Samples of aerated concrete, treated with a polysulfide-based solution with a brush, showed that in this case, water absorption in the sprinkling mode decreases to values of 1.5–2.0%. Discussion. It is noted that during the surface treatment of aerated concrete, a chemically resistant, water-repellent layer 3–3.5 cm thick is formed, which reliably protects the material from the penetration of water and chemicals. The results of the performed experiments give reason to believe that on the surface of the pores of aerated concrete treated with a solution based on calcium polysulfide, as well as on the surface of the pores of previously investigated materials, a nanosized coating is formed of sulfur particles that hydrophobic aerated concrete. Conclusions. Comparison of the results for aerated concrete with excellent data for concrete, brick, shell rock shows that the efficiency for aerated concrete is no less and allows us to recommend the specified solution for long-term protection of the surface of aerated concrete walls.

Keywords

• sulfur
• nanoparticle
• aerated concrete
• water absorption
• strength
• hydrophobicity
• protective coating