Platinum Group Metal Phosphides as Efficient Catalysts in Hydroprocessing and Syngas-Related Catalysis

Abstract

Platinum group metal phosphides are reviewed as catalytic materials for hydroprocessing and syngas-related catalysis. Starting from synthetic procedures leading to highly disperse nano-particular compounds, their properties in the applications are discussed and compared with relevant benchmarks, if available. Regarding their mode of action, two confronting mechanistic scenarios are presented: (i) a cooperative scenario in which catalytic sites of different functionalities are active in hydroprocessing and (ii) single site catalysis, which appears to be the relevant mode of action in syngas-related catalysis and which occurs over “frustrated” active sites.

Keywords

• platinum group metal phosphides
• rhodium phosphide
• hydroprocessing
• HDS
• HDO
• carbon monoxide
• ethene
• propene
• hydroformylation