High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1<i>H</i>-imidazol-2-yl)pyridine

Abstract

Novel iron(II) coordination compounds containing a ligand 2,6-bis(1H-imidazol-2-yl)pyridine (L), having such a composition as [FeL2]SO4·0.5H2O, [FeL2]Br2·H2O, [FeL2](ReO4)2, [FeL2]B10H10∙H2O, [FeL2]B12H12∙1.5H2O had been synthesized and studied using UV-Vis (diffuse reflectance), infrared, extended X-ray absorption fine structure (EXAFS), and Mössbauer spectroscopy methods, as well as X-ray diffraction and static magnetic susceptibility methods. The analysis of the μeff(T) dependence in the temperature range of 80–600 K have shown that all the obtained complexes exhibit a high-temperature spin crossover 1A1 ↔ 5T2.

Keywords

• iron(II) complexes
• 2,6-bis(1<i>H</i>-imidazol-2-yl)pyridine
• X-ray diffraction analysis
• EXAFS
• Mössbauer
• IR