Journal of the Serbian Chemical Society (Apr 2010)
Fluidized bed combustion of pesticide-manufacture liquid wastes
Abstract
Industrial liquid wastes can be in the form of solutions, suspensions, sludges, scums or waste oil and have organic properties. The objective of this work was to demonstrate the technical feasibility of a fluidized bed as a clean technology for burning liquid waste from a pesticide production plant. The combustion of liquid waste mixtures, obtained from realistic samples, was investigated in a pilot scale fluidized bed with quartz sand particles of 0.63–1.25 mm in diameter and 2610 kg/m3 in density at 800–950 °C. To ensure complete combustion of liquid waste and additional fuel, the combustion chamber was supplied with excess air and the U/UmF (at ambient temperature) was in between 1.1 and 2.3. In the fluidized bed chamber, liquid waste, additional liquid fuel and air can be brought into intense contact sufficient to permit combustion in bed without backfire problems. The experimental results show that the fluidized bed furnace offers excellent thermal uniformity and temperature control. The results of the combustion tests showed that degradation of liquid wastes can be successfully realized in a fluidized bed with no harmful gaseous emissions by ensuring that the temperatures of both the bed and the freeboard are not lower than 900 °C.