Analysis of Polymeric Components in Particulate Matter Using Pyrolysis-Gas Chromatography/Mass Spectrometry

Abstract

Particulate matters (PMs) such as PM10 and PM2.5 were collected at a bus stop and were analyzed using pyrolysis-gas chromatography/mass spectrometry to identify organic polymeric materials in them. The major pyrolysis products of the PM samples were isoprene, toluene, styrene, dipentene, and 1-alkenes. The pyrolysis products generated from the PM samples were identified using reference polymeric samples such as common rubbers (natural rubber, butadiene rubber, and styrene-butadiene rubber), common plastics (polyethylene, polypropylene, polystyrene, and poly(ethylene terephthalate)), plant-related components (bark, wood, and leaf), and bitumen. The major sources of the principal polymeric materials in the PM samples were found to be the abrasion of the tire tread and asphalt pavement, plant-related components, and lint from polyester fabric. The particles produced by the abrasion of the tire tread and asphalt pavement on the road were non-exhaustive sources, while the plant-related components and lint from polyester fabric were inflowed from the outside.

Keywords

• particulate matter
• organic polymeric component
• pyrolysis-gas chromatography/mass spectrometry
• tire tread wear
• asphalt pavement wear