Fabrication of Tin and Zinc Gas Diffusion Electrodes for Electrochemical Reduction of Carbon Dioxide

Abstract

This study explores the electrochemical reduction of carbon dioxide (CO2) using tin (Sn) and zinc (Zn) catalyst-loaded gas diffusion electrodes (GDEs). The research explores the influence of electrolytic potential and catalyst loading on the efficiency of CO2 conversion to valuable chemicals, specifically formic acid and carbon monoxide. The best Sn loading for Sn-loaded GDEs, according to the morphological study, is 7 mg.cm-2, which results in higher current density (0.33 mA.cm-2) and current efficiency (36%). An electrolytic potential of -1.3 V Vs. Ag/AgCl is identified as optimal for Sn GDEs, offering a balance between high current efficiency (35%) and controlled current density. For Zn-loaded GDEs, an optimal loading of 5 mg.cm²- yields the highest current efficiency of 19.4% and a peak current density of 0.28 mA.cm²- at an electrolytic potential of -1.55 V Vs. Ag/AgCl, in addition to highlighting the crucial role that catalyst loading and electrolytic potential play in enhancing CO2 reduction efficiency, this research offers insightful information for environmentally friendly CO2 conversion technology.

Keywords

• electrochemical reduction, carbon dioxide, catalyst loading, current efficiency, gas diffusion electrodes