Influence of Ti Addition on the Strengthening and Toughening Effect in CoCrFeNiTi_x Multi Principal Element Alloys

Abstract

Multi principal element alloys have attracted interests as a promising way to balance the bottleneck of the “inverse relationship” between high hardness and high fracture toughness. In the present study, the authors demonstrate the effects of Ti addition on the microstructures and mechanical properties of the CoCrFeNiTix alloys (x values in molar ratio, x = 0.7, 1.0, and 1.2), which exhibits a multi-phase structure containing face-centered cubic phase and various secondary phases, such as sigma, Laves, and (Cr,Fe)-rich phase. Throughout the combined experimental examination and modeling, we show that superb hardness (~9.3 GPa) and excellent compressive strength (~2.4 GPa) in our alloy system are attributed to solid-solution strengthening of the matrix and the formation of hard secondary phases. In addition, high indentation fracture toughness is also derived from the toughening mechanism interplay within the multiple-phase microstructure. At the fundamental level, the results suggest that multi-principal element alloys containing dual or multi-phase structures may provide a solution for developing structural alloys with enhanced strength-toughness synergy.

Keywords

• multi-principal element alloys
• high entropy alloys
• topologically closed packed phase
• solid-solution strengthening
• indentation fracture toughness