Value-Added Products from Urea Glycerolysis Using a Heterogeneous Biosolids-Based Catalyst

Abstract

Although thermal hydrolysis of digested biosolids is an extremely promising strategy for wastewater management, the process economics are prohibitive. Here, a biosolids-based material generated through thermal hydrolysis was used as a catalyst for urea glycerolysis performed under several conditions. The catalytic system showed remarkable activity, reaching conversion values of up to 70.8 ± 0.9% after six hours, at 140 °C using a catalyst/glycerol weight ratio of 9% and an air stream to remove NH3 formed during the process. Temperature played the most substantial role among reaction parameters; increasing temperature from 100 °C to 140 °C improved conversion by 35% and glycidol selectivity by 22%. Furthermore, the catalyst retained good activity even after the fourth catalytic run (conversion rate of 56.4 ± 1.3%) with only a slight decrease in glycidol selectivity. Thus, the use of a biosolids-based catalyst may facilitate conversion of various glycerol sources (i.e., byproduct streams from biodiesel production) into value-added products such as glycidol, and may also improve the economic feasibility of using thermal hydrolysis for treatment of biosolids.

Keywords

• biosolids
• urea glycerolysis
• glycidol
• glycerol carbonate
• catalyst