Structure and electric properties of cerium substituted SrBi1.8Ce0.2Nb2O9 and SrBi1.8Ce0.2Ta2O9 ceramics

Abstract

SrBi1.8Ce0.2Nb2O9 (SBCN) and SrBi1.8Ce0.2Ta2O9 (SBCT) powders were prepared via solid-state reaction method. X-ray diffraction analysis reveals that the SBCN and SBCT powders have the single phase orthorhombic Aurivillius structure at room temperature. The contribution of Raman scattering and FTIR spectroscopy of these samples were relatively smooth and resemble each other. The calcined powders were uniaxially pressed and sintered at 1250 °C for 8 h to obtaine dense ceramics. Dielectric constant, loss tangent and AC conductivity of the sintered Ce-doped SrBi2Nb2O9 and SrBi2Ta2O9 ceramics were measured by LCR meter. The Ce-doped SBN (SBCN) ceramics have a higher Curie temperature (TC) and dielectric constant at TC (380 °C and ε′ ∼3510) compared to the Ce-doped SBT (SBCT) ceramics (330 °C and ε′ ∼115) when measured at 100 Hz. However, the Ce-doped SBT (SBCT) ceramics have lower conductivity and dielectric loss.

Keywords

• SrBi2Nb2O9
• SrBi2Ta2O9
• Ce-doping
• structure
• conductivity
• dielectric measurments