An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a <i>Pseudo-Geminal</i> [2.2]Paracyclophane 1,3-Dithia-2-Thione

Abstract

The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)[2.2]paracyclophane, a new compound of interest for many researchers.

Keywords

• [2.2]paracyclophanes
• dithiocarbamates
• 1,3-dithiolium salts
• trithiones