Nanomaterials (Mar 2022)
Metal–Organic-Framework-Derived Ball-Flower-like Porous Co<sub>3</sub>O<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> Heterostructure with Enhanced Visible-Light-Driven Photocatalytic Activity
Abstract
A porous ball-flower-like Co3O4/Fe2O3 heterostructural photocatalyst was synthesized via a facile metal–organic-framework-templated method, and showed an excellent degradation performance in the model molecule rhodamine B under visible light irradiation. This enhanced photocatalytic activity can be attributed to abundant photo-generated holes and hydroxyl radicals, and the combined effects involving a porous structure, strong visible-light absorption, and improved interfacial charge separation. It is notable that the ecotoxicity of the treated reaction solution was also evaluated, confirming that an as-synthesized Co3O4/Fe2O3 catalyst could afford the sunlight-driven long-term recyclable degradation of dye-contaminated wastewater into non-toxic and colorless wastewater.
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