Acta Crystallographica Section E (Jul 2009)

Dichlorido[1-(8-quinolyliminomethyl)-2-naphtholato]iron(III)

  • Daisuke Urakami,
  • Katsuya Inoue,
  • Shinya Hayami

DOI
https://doi.org/10.1107/S1600536809022880
Journal volume & issue
Vol. 65, no. 7
pp. m800 – m800

Abstract

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The FeIII ion in the title complex, [FeCl2(C20H13N2O)], has a distorted square-pyramidal coordination formed by one O atom and two N atoms from a tridentate 1-(8-quinolyliminomethyl)-2-naphtholate ligand and two Cl atoms. In the crystal structure, molecules form a column structure along the a axis through π–π stacking interactions, with centroid–centroid distances of 3.657 (1) and 3.818 (2) Å. Weak C—H...Cl interactions are observed between the columns.